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Cai YB, Huang FL, Wei QF, Song L, Hu Y, Ye Y, Xu Y, Gao WD (2008) Polymer Degradation and Stability 93(12), 2180-2185.
文章来源:WOS    作者:SKLFS    发布时间:2011-08-16

Cai YB, Huang FL, Wei QF, Song L, Hu Y, Ye Y, Xu Y, Gao WD (2008) Structure, morphology, thermal stability and carbonization mechanism studies of electrospun PA6/Fe-OMT nanocomposite fibers. Polymer Degradation and Stability 93(12), 2180-2185. [In English]

Web link: http://dx.doi.org/10.1016/j.polymdegradstab.2008.08.003

Keywords:

Electrospinning; Nanocomposite fibers; Fe-OMT; Thermal stability; Carbonization mechanism; layered-silicate nanocomposites; carbon nanotubes; catalytic combustion; montmorillonite; polypropylene; degradation; nylon-6; polymer; salts

Abstract: In the present work, Fe-montmorillonite (Fe-MMT) was synthesized by hydrothermal method, and then was modified by cetyltrimethyl ammonium bromide (CTAB). The polyamide 6 (PA6)/organic-modified Fe-montmorillonite (Fe-OMT) nanocomposite fibers were prepared by a facile compounding and electrospinning. The catalyzing carbonization studies of the Fe-OMT based on PA6 nanocomposite fibers were performed. It was found from High-resolution electron microscopic (HREM) observations that the silicate clay layers were well dispersed within the nanocomposite fibers and was oriented along the fiber axis. The Scanning electron microscopic (SEM) images indicated that the nanofibers were randomly distributed to form the fibrous web and the Fe-OMT additives decreased the diameters of nanocomposite fibers. The Thermogravimetric analyses (TGA) revealed that the loading of the Fe-OMT led to the crosslinking of the PA6, promoted the charred residue yield and catalytic graphitization effect. The structure and morphology of the purified charred residue, characterized by XRD, HREM, Selected area electron diffraction (SAED) and Laser Raman spectroscopic (LR), approved further the presence of graphite sheets. The possible catalyzing carbonization mechanisms included: (1) catalyzing effect of the Fe3(+), which promoted the crosslinking of polymer, (2) Hofmann degradation of the Fe-OMT, whose degraded products had also positive role in promoting crosslinking reactions, (3) gas barrier properties of the nano-dispersed silicate clay layers stopped or reduced the releases of the pyrolytic products, which was dehydrogenated and aromatized to form graphite. (C) 2008 Elsevier Ltd. All rights reserved.

 
 
相关链接
Cai YB, Huang FL, Wei QF, Song L, Hu Y, Ye Y, Xu Y, Gao WD (2008) Polymer Degradation and Stability 93(12), 2180-2185.
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