Z. M. Bai, S. D. Jiang, G. Tang, Y. Hu, L. Song and R. K. K. Yuen (2014) Enhanced thermal properties and flame retardancy of unsaturated polyester-based hybrid materials containing phosphorus and silicon. Journal/Polymers for Advanced Technologies 25 223-232. [In English]
Web link: http://dx.doi.org/10.1002/pat.3227
Keywords: unsaturated polyester; Sol-gel; pyrolysis; flame retardancy; COMBUSTION BEHAVIORS; EPOXY-RESINS; COMPOSITES; DEGRADATION; NANOCOMPOSITES; DECOMPOSITION; SPECTROSCOPY; MECHANISM

Abstract: A phosphorus and silicon containing liquid monomer (9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide-vinyltrimethoxysilane (DOPO-VTS)) was synthesized by the reaction between DOPO and VTS. DOPO-VTS and methacryloxypropyltrimethoxylsilane were introduced into unsaturated polyester resin to prepare flame retardant UPR/SiO2 (FR-UPR/SiO2) hybrid materials by sol-gel method and curing process. DOPO-VTS contributes excellent flame retardancy to UPR matrix, which was confirmed by the limiting oxygen index and microscale combustion calorimeter results. The thermogravimetric analysis (TGA) results indicate that the FR-UPR/SiO2 hybrid materials possess higher thermal stability and residual char yields than those of pure UPR at high temperature region. The thermal degradation of materials was investigated by TGA/infrared spectrometry (TG-IR) and real-time infrared spectrometry (RT-IR), providing insight into the thermal degradation mechanism. Moreover, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used to explore the morphologies and chemical components of the residual char. Copyright (c) 2013 John Wiley & Sons, Ltd.